矿用全尾砂纤维增强水泥基复合材料力学性能试验研究

    Experimental study on mechanical properties of fiber-reinforced cementitious composites using total mine tailings as aggregate

    • 摘要: 针对地下矿山巷道支护用喷射混凝土韧性不足、易开裂的实际问题。本文提出一种由金属矿山尾砂作为骨料,硅酸盐水泥、高炉矿渣和硅灰作为胶凝材料,聚乙烯(PE)纤维作为增强材料的高韧性矿用水泥基复合材料。为验证该新型支护材料的力学性能优势,分别选取骨料种类(铜镍矿尾砂和金矿尾砂)、水胶比(0.22、0.24和0.26)、纤维长度(6 mm、12 mm和18 mm)和养护龄期(7 d、14 d和28 d)作为变量,制备了185个标准试样,分别开展了单轴拉伸、压缩和剪切试验。同时,采用扫描电子显微镜对新型支护材料的微观结构进行了测试分析。研究结果表明:①采用铜镍矿尾砂和金矿尾砂作为骨料制备的矿用全尾砂纤维增强水泥基复合材料表现出明显的应变硬化特征,其28 d时抗拉强度分别为2.87 MPa和2.22 MPa,对应的拉伸应变分别达到7.84%和8.28%,明显高于普通喷射混凝土;②矿用全尾砂纤维增强水泥基复合材料抗压强度随养护时间呈现增长趋势,7 d和28 d的最大平均抗压强度分别为16.23 MPa和45.66 MPa;③骨料矿物组分与粒径差异会改变基体水化进程及界面微观结构,不同尾砂制备的纤维增强复合材料黏聚力、内摩擦角随养护龄期呈现差异化演化特征,直接影响材料长期抗剪稳定性能;④矿用全尾砂纤维增强水泥基复合材料的主要破坏模式为纤维拔出和纤维桥连,主要原因可能归结于其相对偏小的平均粒径。本研究提出的矿用纤维增强复合材料有望进一步丰富金属矿山巷道支护材料类型,助力巷道围岩稳定控制技术发展。

       

      Abstract: Aiming at the problems of insufficient toughness and frequent cracking of shotcrete used for underground mine roadway support, this paper proposes a high-toughness cementitious composite for mining applications, using metal mine tailings as aggregate, Portland cement, blast furnace slag and silica fume as cementitious materials, and polyethylene(PE) fibers as reinforcing material. To verify the mechanical performance advantages of this new support material, a total of 185 standard specimens are prepared with four variables, namely tailings type(copper-nickel mine tailings and gold mine tailings), water-binder ratio(0.22, 0.24 and 0.26), fiber length(6 mm, 12 mm and 18 mm) and curing age(7 d, 14 d and 28 d). Uniaxial tensile, compressive and shear tests are carried out on all specimens, and scanning electron microscopy(SEM) is adopted to characterize the microstructure of the proposed material. The results show that fiber-reinforced cementitious composites using copper-nickel total mine tailings and gold total mine tailings as aggregate exhibit significant strain-hardening behavior. At the curing age of 28 d, their tensile strengths reach 2.87 MPa and 2.22 MPa, with corresponding tensile strains of 7.84% and 8.28%, respectively, both superior to those of conventional shotcrete. The compressive strength of the proposed composites increases with curing age, with the maximum average compressive strengths of 16.23 MPa at 7 d and 45.66 MPa at 28 d. Differences in mineral composition and particle size of aggregates alter the hydration process of matrix and the interfacial microstructure. The cohesion and internal friction angle of fiber-reinforced composites prepared from different tailings exhibit differentiated evolution characteristics with curing age, which directly affects the long-term shear stability of materials. The primary failure modes of the composites include fiber pull-out and fiber bridging, which can be attributed to the relatively small average particle size of total mine tailings. The proposed fiber-reinforced composite for mining applications can enrich the types of support materials for metal mine roadways and facilitate the development of surrounding rock stability control technology.

       

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