基于MIF法的几种黏土矿物X射线衍射定量研究

    The quantitative X-ray diffraction analysis of several kinds of clay minerals based on mineral intensity factor method

    • 摘要: 国际上近年来兴起了一种新的黏土矿物定量方法——矿物强度因子(mineral intensity factor,MIF)法。该法通过某种黏土矿物特定、唯一的MIF值进行定量,较之国内主要使用的修正Schultz法和参比强度(reference intensity ratio,RIR)法更为准确,然而已报道的黏土矿物MIF值并不全面,缺失了几种常见的重要黏土矿物MIF值。本文选取不同产地的纯相黏土矿物,通过人工配样的方法,对已有的MIF值进行验证,并增补了伊利石和蒙脱石的MIF值, 蒙脱石的MIF值为0.093,伊利石的MIF值为0.084。

       

      Abstract: Clay mineral is one of the most important components of soil and rock, and its quantification of geological samples is of great significance to the study of mineralogical characteristics and geological evolution.X-ray diffraction (XRD) analysis is the most widely used method for the quantitative analysis of clay minerals.Modified Schultz method and reference intensity ratio (RIR) method are traditionally widely selected for quantification of clay minerals.However, quantification accuracy of the two methods is low.Recently, a new quantitative analysis method of clay mineral, mineral intensity factor (MIF) method, is confirmed to be more accurate.This method quantifies clay mineral using the specific MIF value which is believed to the unique value for each kind of clay mineral.However, several MIF factors of clay minerals such as montmorillonite and illite have not been given in the previous reports until now.In this paper, the accuracy of the MIF method was evaluated by quantifying artificially mixed samples composed by different pure clay minerals.Moreover, MIF factors of montmorillonite and illite were obtained.The MIF factors of montmorillonite and illite are 0.093 and 0.084, respectively.

       

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