铜粗精矿的提质增效试验研究

    Experimental study on improving quality and benefits of rough copper concentrates

    • 摘要: 某铜选厂原矿铅锌品位不足0.20%,但受原铜捕收剂黏附作用的影响,铅锌极易混入到铜精矿中,导致铜粗精矿中铅锌含量超标,严重影响了铜精矿品质。矿石性质表明,铅锌主要以硫化矿形式存在,解离程度好,具有一定的综合利用价值。为了解决上述问题,通过选矿小型试验,将原铜浮选作业的捕收剂Z200改为乙基黄药,降低了铜捕收剂对铅锌的黏附作用,为后续从铜精矿中综合利用铅锌矿物创造了有利条件。对于铜粗精矿,采用硫化钠为脱药剂,多硫化物TY为铜抑制剂,乙硫氮为铅捕收剂,不仅从铜粗精矿中获得了铅品位大于50%的铅精矿,而且铅锌合计含量可降至8%以下,铜品位可提高至17%左右,铜总回收率仍可维持在82%左右,实现了铜粗精矿提质增效,经济效益显著增加,为国内外铜选厂的生产提供参考和借鉴。

       

      Abstract: The lead and zinc contents of the raw ore from a copper concentrator are both less than 0.20%, but due to the adhesion of the used copper collectors, the lead and zinc minerals could be easily mixed into copper concentrates, which exceeds the lead and zinc standard and affected the quality of the copper concentrates seriously.According to the ore property analysis results, the lead and zinc minerals mainly existed in the form of sulfides, and both have higher liberation degree, which indicats a certain comprehensive utilization value.To solve the above problems, based on the results of abundant lab tests, the used collector Z200 of copper flotation is replaced by ethyl xanthate, which reduces the adhesion affect and creates favorable conditions for the subsequent lead and zinc comprehensive utilization of rough copper concentrates.For copper rough concentrates, sodium sulfide has been adopted for reagent removal process, polysulfide TY has been selected as copper depressant, and ethyl thio carbamate has been used as lead collector.Not only a lead concentrate which contains more than 50% Pb is obtained from the the rough copper concentrates, but also the lead and zinc contents are reduced to less than 8%.Finally, the copper grade increases to about 17% with a maintained recovery of about 82%, which improves the quality and increases the benefits of copper concentrates, all these could be reference for similar copper concentrators.

       

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