钢渣基复合充填胶凝材料开发及配比优化

    Development of steel slag based composite filling cementitious material and optimization of its proportion

    • 摘要:

      由于钢渣具有难磨、活性低、体积膨胀性等特性,目前尚未得到充分利用。为提高钢渣利用率,以某铁矿选矿全细尾砂为骨料,利用矿山周边的钢渣、矿渣、脱硫石膏等固废资源协同开发新型低成本充填胶凝材料,并进一步优化配比。首先,对试验材料进行物化分析,在此基础上进行胶凝材料配比试验及配比优化试验,确定充填胶凝材料配比;其次,进行充填体胶砂强度验证试验和料浆稳定性测试,以分析强度、泌水率和分层度的影响规律;最后,进行二次多项式逐步回归分析,并以充填成本为优化目标建立料浆配比优化函数关系式,得到细尾砂骨料钢渣基复合充填胶凝材料优化配比为钢渣粉∶脱硫石膏∶矿渣粉=4∶1∶5,当料浆浓度为64%、胶砂比为1∶5时,其胶结体强度远高于PO.42.5水泥,成本低于PO.42.5水泥约35%。研究成果可为冶金矿山绿色清洁生产提供新的途径。

       

      Abstract:

      Due to the factors such as hard grinding, low activity and volume expansion of steel slag, it has not been fully utilized at present.In order to improve the utilization rate of steel slag, taking the full fine tailings of an iron ore as the aggregate, utilize the steel slag, slag, desulfurization gypsum and other solid waste resources around the mine to develop new low-cost filling cementitious materials, and further optimize the ratio.Firstly, the physicochemical analysis of the test material is carried out.On this basis, the cementitious material ratio test and the ratio optimization test are carried out.Determining the ratio of filling cementitious materials.Secondly, the backfill mortar strength test and slurry stability test are carried out.To analyze the influence law of strength, bleeding rate and stratification.Finally, a quadratic polynomial stepwise regression analysis is performed, and taking the filling cost as the optimization goal to establish the optimal function relation of slurry ratio.The optimal proportion of fine tailings aggregate steel slag based composite filling cementitious material is obtained as follows steel slag 40%, slag 50%, desulfurization gypsum 10%.When the slurry concentration is 64% and the mortar ratio is 1∶5, it’s cement strength is much higher than PO.42.5 cement.The cost is about 35% lower than PO.42.5 cement.The research results can explore a new way for the green and clean production of metallurgical mines.

       

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