泡沫凝胶稳定性及其结构演化特征研究

    Study on the stability of foamed gel and its structural evolution characteristics

    • 摘要: 泡沫凝胶是一种高效的煤自燃防治材料,该材料结合了泡沫的流动性和堆积性、凝胶的耐温性等防灭火特性。本文从泡沫凝胶的形成原理、结构演化、稳定性和流动性等阐述了泡沫凝胶的防灭火特征。泡沫凝胶主要由发泡剂、交联剂和水等通过物理发泡和成胶反应后形成,其形成过程分为两个阶段:第一阶段为物理发泡,形成泡沫液;第二阶段将交联剂加入泡沫,通过胶凝反应后生成泡沫凝胶。第一阶段泡沫凝胶主要体现泡沫的流动性和堆积性,第二阶段随着胶体量的增加,泡沫凝胶体现胶体的耐温性,同时可通过交联剂的添加量控制凝胶的成胶时间。泡沫凝胶的基础结构与水基泡沫的结构相同,不同的是凝胶颗粒构成了泡沫凝胶的基础骨架,减缓了重力排液和泡沫歧化速率。泡沫凝胶结构的演化过程包括液膜破裂、成胶和骨架坍塌等,最终形成凝胶层充填遗煤裂隙。泡沫凝胶在采空区中的流动受注浆压力、重力和阻力的综合作用,横向流动速度大于纵向流动速度,其扩散前峰轮廓线为椭球形。本文研究成果为泡沫凝胶的科学应用提供了有力支撑。

       

      Abstract: Foamed gel is a kind of highly efficient coal spontaneous combustion control material, which combines the fluidity and accumulation of foam, high temperature resistance of the gel and other fire-fighting properties. This paper describes the formation principle, structural evolution, stability and fluidity of foamed gel. Foamed gel is mainly formed by foaming agent, crosslinking agent and water through physical foaming and gelling reaction, the formation process is divided into two stages, the first stage is physical foaming, forming foam solution. In the second stage, the crosslinking agent is added to the foam and the foamed gel is formed after the gelling reaction. The first stage, foamed gel mainly reflects the fluidity and accumulation of foam, the second stage, with the increase of colloidal amount, foamed gel reflects the temperature resistance of colloidal, at the same time, the gel formation time can be controlled by the amount of crosslinking agent. The basic structure of the foamed gel is the same as that of the water-based foam. The gel particles form the basic skeleton of the foamed gel, which slows down the gravity drainage and the disproportionation rate of the foam. The evolution process of foamed structure of gel includes liquid film rupture, gel formation and skeleton collapse, and finally gel layer filling coal fracture. The flow of foamed gel in goaf is affected by grouting pressure, gravity and resistance. The transverse flow velocity is greater than the longitudinal flow velocity, and the contour of the pre-diffusion peak is ellipsoid. The research results provide a strong support for the scientific application of foamed gel.

       

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