西北荒漠化地区风化煤腐植酸提取技术及应用研究进展

    Research progress on extraction technology and application of humic acid from weathered coal in desertification area of Northwest China

    • 摘要: 我国风化煤储量丰富且腐植酸含量高,因含氧量高、发热量低,用于发电、炼焦等工业生产经济效益不高,直接燃烧或作为原粉用于改良土壤等传统利用方式会产生环境污染且效能较低,但从中提取高生化活性的腐植酸可广泛应用于农业、工业、医药和材料等领域。本文首先论述了风化煤腐植酸碱提取法、酸提取法和微生物溶解法等提取技术,包括各技术的反应机理、优缺点和研究进展。碱提取法中重点阐述了硝酸氧化预处理、过氧化氢氧化预处理、超声波活化氧化预处理及其他氧化预处理方法;酸提取法中分析了提取风化煤中黄腐酸的机理与研究现状;微生物溶解法中梳理了微生物菌株选择方法、可选种类、降解机理和降解影响因素,其中,降解机理包括碱作用机理、螯合剂作用机理、表面活性剂作用机理、酶作用机理和ABCDE综合作用机理。其次总结了腐植酸在农业、工业、环境保护和医药四个领域的应用。最后围绕西北荒漠化地区腐植酸的巨大发展优势,对腐植酸的提取和应用进行了展望,以期寻找一种更加清洁高效的风化煤腐植酸提取技术,推动低阶煤的高效利用。

       

      Abstract: The weathered coal in China is rich in reserves and has high humic acid content. Due to its high oxygen content and low calorific value, it is not cost-effective for industrial production such as power generation and coking, direct combustion or as raw powder used to improve soil and other traditional utilization methods will produce environmental pollution and low efficiency, but the humic acid extracted from high biochemical activity can be widely used in agriculture, industry, medicine and materials and other fields. Firstly, the extraction techniques of humic acid from weathered coal such as alkali extraction, acid extraction and microbial dissolution are discussed, including the reaction mechanism, advantages and disadvantages and research progress of each method. In alkali extraction method, the pretreatment of nitric acid oxidation, hydrogen peroxide oxidation, ultrasonic activation oxidation and other oxidation pretreatment methods are emphasized. The mechanism and research status of extracting fulvic acid from weathered coal in acid extraction method are analyzed. In the method of microbial dissolution, the selection method of microbial strains, the available types, the degradation mechanism and the influencing factors of degradation are reviewed, the degradation mechanism including alkali mechanism, chelating agent mechanism, surfactant mechanism, enzyme mechanism and ABCDE comprehensive mechanism. Then, the applications of humic acid in agriculture, industry, environmental protection and medicine are summarized. Finally, based on the huge development advantages of humic acid in the desertification area of Northwest China, the extraction and application of humic acid are prospected, in order to find a cleaner and more efficient extraction technology of humic acid from weathered coal and promote the efficient utilization of low-rank coal.

       

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