从浮选尾矿中综合回收钨的试验研究

    Experimental study on comprehensive recovery of tungsten from flotation tailings

    • 摘要: 浮选尾矿中WO3的含量为0.130%,具有综合回收价值。该尾矿中矿物成分较多,其中,钨矿物主要为黑钨矿,其次为白钨矿、钨华,其他金属矿物主要为黄铁矿,以及微量的闪锌矿、方铅矿、褐铁矿、菱铁矿、磁铁矿等。脉石矿物主要为石英,其次为钙铁榴石,少量的方解石、伊利石、钾长石等。在各粒级钨金属分布中微、细粒级的钨占有率高,若此类微、细粒级不能脱除,将严重影响钨的回收效果。试验研究了浮选方案和重选方案,均获得较好效果。采用浮选方案,开路试验获得产率1.32%、WO3品位2.94%、回收率29.68%的钨总精矿,对该钨总精矿,经过三次开路加温精选试验,获得作业产率3.18%、作业回收率66.71%、WO3品位61.15%的钨精矿,全流程闭路试验获得产率0.06%、WO3品位60.62%、回收率34.82%的钨精矿;采用重选方案,其全流程试验获得产率0.24%、WO3品位19.53%、回收率36.65%的钨总精矿,其中,产率约0.01%的钨精矿WO3品位达到66.58%。由于浮选方案工艺流程较复杂、药剂成本高且回水残留药剂对主流程浮选有比较严重的影响,对环境也造成一定影响。因此,为了达到高效、低成本且环境友好的效果,研究推荐采用重选的原则方案。

       

      Abstract: The content of WO3 in flotation tailings of a mine is 0.130%, which has comprehensive recovery value. There are many mineral components in the tailings, among which tungsten minerals are mainly wolframite, a small amount of scheelite and wolframite, and other metal minerals are mainly pyrite, and a small amount of sphalerite, galena, limonite, siderite and magnetite. The main gangue is quartz, followed by andradite, with a small amount of calcite, illite and potash feldspar. In the distribution of tungsten metal in each particle size, the proportion of micro and finegrained tungsten is high, and the micro and finegrained tungsten cannot be removed, which will seriously affect the recovery effect of tungsten. The flotation and gravity separation schemes are studied in this experiment, and good results are obtained. Using the flotation scheme, the total tungsten concentrate with a yield of 1.32%, WO3 grade of 2.94% and recovery of 29.68% is obtained by open circuit test. The tungsten concentrate with an operating yield of 3.18%, operating recovery of 66.71% and WO3 grade of 61.15% are obtained through three open-circuit heating cleaning tests, and the tungsten concentrate with yield of 0.06%, WO3 grade of 60.62% and recovery rate of 34.82% are obtained by closed-circuit test in the whole process. Using the gravity separation scheme, the total tungsten concentrate with a yield of 0.24%, WO3 grade of 19.53% and recovery rate of 36.65% are obtained in the whole process test, in which the WO3 grade of tungsten concentrate with yield of about 0.01% reached 66.58%. Due to the flotation process is complex, the reagent cost is high, and backwater residual reagent has a serious impact on the main flotation process and the environment, in order to achieve the effect of high efficiency, low cost and environmental friendliness, the principle scheme of gravity separation is finally recommended.

       

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