不同磨矿方式对细鳞片石墨浮选、鳞片保护及解离行为的影响

    Effect of different grinding methods on flotation, flake protection and liberation behavior of fine flake graphite

    • 摘要: 为了促进细鳞片石墨矿的开发和利用,本文研究了搅拌磨、球磨和棒磨对细鳞片石墨浮选、鳞片保护及解离行为的影响。浮选动力学试验结果表明细度(−0.074 mm)占比82.5%条件下,搅拌磨产品的浮选速率、浮选精矿回收率,以及精矿固定碳含量要显著高于球磨产品和棒磨产品。在获得固定碳含量相同的精矿产品时,搅拌磨产品的浮选精矿回收率显著高于球磨产品和棒磨产品的浮选精矿,有助于细鳞片石墨的高效回收。不同细度条件下的磨矿实验结果表明,搅拌磨产品的浮选精矿固定碳含量和回收率也高于传统棒磨产品和球磨产品的浮选精矿。筛分实验结果表明在细度(−0.074 mm)小于82.5%时,搅拌磨产品的浮选精矿中+0.15 mm的大鳞片石墨产率高于传统的棒磨产品和球磨产品。相反,细度(−0.074 mm)大于82.5%,搅拌磨对大鳞片石墨的损伤程度比球磨和棒磨更为严重。不同磨矿产品的浮选精矿SEM观察结果表明搅拌磨的冲击作用弱于球磨和棒磨,且易于打破脉石与石墨鳞片之间的黏结促进细鳞片石墨的高效解离。搅拌磨是一种非常适用于细鳞片石墨的磨矿方法。

       

      Abstract: In order to promote the development and utilization of fine flake graphite ore, this paper studies the effects of stirred mill, ball mill and rod mill on the flotation, flake protection and dissociation behavior of fine flake graphite. The results of the flotation kinetics test show that under the condition of a fineness of −0.074 mm accounting for 82.5%, the flotation rate of the stirred mill product, the recovery rate of the flotation concentrate, and the fixed carbon content of the concentrate are significantly higher than those of the ball mill product and the rod mill product. The flotation concentrate recovery of stirred mill products is significantly higher than that of ball mill products and rod mill products when obtaining concentrate products with the same fixed carbon content, which is conducive to the efficient recovery of fine flake graphite. The grinding experiment results under different fineness conditions show that the fixed carbon content and recovery of the flotation concentrate of the stirred mill products are also higher than those of the flotation concentrates of the traditional rod mill products and ball mill products. The screening experiment results show that when the fineness (−0.074 mm) is less than 82.5%, the yield of +0.15 mm large flake graphite in the flotation concentrate of the stirred mill products is higher than that of the traditional rod mill products and ball mill products. On the contrary, the damage caused by the stirred mill to the large flake graphite is more severe than that of the ball mill and rod mill when the fineness (−0.074 mm) is greater than 82.5%. The SEM observation results of flotation concentrates of different grinding products show that the impact effect of the stirred mill is weaker than that of the ball mill and the rod mill, and it is easy to break the adhesion between ganglia and graphite flakes, promoting the efficient dissociation of fine flake graphite. Stirred grinding is a grinding method that is very suitable for fine flake graphite.

       

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