王常辉,王奕博,张瀚霖,等. “高碳高湿”煤气化细渣特性分析及干燥动力学研究[J]. 中国矿业,2024,33(9):204-211. DOI: 10.12075/j.issn.1004-4051.20240234
    引用本文: 王常辉,王奕博,张瀚霖,等. “高碳高湿”煤气化细渣特性分析及干燥动力学研究[J]. 中国矿业,2024,33(9):204-211. DOI: 10.12075/j.issn.1004-4051.20240234
    WANG Changhui,WANG Yibo,ZHANG Hanlin,et al. Characteristic analysis and drying kinetics of “high carbon and high moisture” coal gasification fine slag[J]. China Mining Magazine,2024,33(9):204-211. DOI: 10.12075/j.issn.1004-4051.20240234
    Citation: WANG Changhui,WANG Yibo,ZHANG Hanlin,et al. Characteristic analysis and drying kinetics of “high carbon and high moisture” coal gasification fine slag[J]. China Mining Magazine,2024,33(9):204-211. DOI: 10.12075/j.issn.1004-4051.20240234

    “高碳高湿”煤气化细渣特性分析及干燥动力学研究

    Characteristic analysis and drying kinetics of “high carbon and high moisture” coal gasification fine slag

    • 摘要: “高碳高湿”煤气化细渣固定碳含量高、干基高位发热量高,但由于其水分高达70%左右,导致收到基低位发热量低,严重影响其进一步综合利用。宁夏水煤浆炉气化细渣样品灰分为50.04%,干基高位发热量达到3 809 cal/g,具有较高利用价值,但该煤气化细渣滤饼水分高达69.2%,收到基低位发热量仅为790 cal/g,进一步降低滤饼水分,是有效提高其综合利用效率的关键。该细渣含有SiO2、Fe2O3、CaSi2等矿物,微观形貌主要由絮状结构、独立球状颗粒、絮状球状混杂结构组成,且絮状结构表面的元素主要为C和O,球状颗粒表面的元素主要为O、C和Fe,同时,形貌观察可知该煤气化细渣孔隙发达,脱水困难。对细渣滤饼样品进行干燥脱水实验,在不同的干燥温度下,干燥速率呈现先增大后逐渐减小的变化规律。干燥动力学模型中,半经验模型相较于半理论模型更能准确描述该煤气化细渣的干燥脱水特性,其中,Page模型拟合效果最为突出,且形式最为简单,拟合得到干燥脱水的动力学方程。

       

      Abstract: “High carbon and high moisture” coal gasification fine slag has a high fixed carbon content and dry based high calorific value. However, due to its high moisture content of about 70%, it leads to low received base low calorific value, seriously affecting its further comprehensive utilization. The ash content of the gasification fine slag sample in Ningxia coal-water slurry furnace is 50.04%, and the dry based high calorific value reaches 3 809 cal/g, which has high utilization value. However, the moisture content of the gasification fine slag filter cake is as high as 69.2%, and the received base low calorific value is only 790 cal/g. Further reducing the moisture content of the filter cake is the key to effectively improving its comprehensive utilization efficiency. The fine slag contains minerals such as SiO2, Fe2O3, CaSi2, etc. The microstructure is mainly composed of flocculent structure, independent spherical particles, and flocculent spherical mixed structure. The elements on the surface of the flocculent structure are mainly C and O, while the elements on the surface of the spherical particles are mainly O, C, and Fe. At the same time, the morphology observation shows that the pores of the coal gasification fine slag are developed and dehydration is difficult. Drying and dehydration experiments are conducted on fine slag filter cake samples, and the drying rate shows a trend of increasing first and then gradually decreasing at different drying temperatures. In the drying kinetics model, the semi empirical model can more accurately describe the drying and dehydration characteristics of the coal gasification fine slag compared to the semi theoretical model. Among them, the Page model has the most prominent fitting effect and the simplest form, fitting the drying and dehydration kinetics equation.

       

    /

    返回文章
    返回