磷尾矿基矿山复垦基质土在矿山生态修复中的应用分析

    Analysis on application of reclaimed substrate soil in mine ecological restoration of phosphate tailings base

    • 摘要: 昆阳磷矿地处云南省昆明市滇池水质保护流域,矿山复垦及生态修复对滇池水域环境保护意义重大。以昆阳磷矿浮选产生的大量磷尾矿进行矿山复垦基质土改良,通过土柱淋溶试验提出有效生态修复方法,并在中试试验中验证该方法的可行性与有效性,为流域矿山复垦提供新思路与方向。在实验室研究阶段,以磷尾矿为基质,选取黑页岩、填料、堆肥、固磷剂、团粒剂为改良剂,探究改良剂对基质土入渗率、pH值、容重及饱和含水量等性质的影响因素,明确各改良剂不同添加量与基质土上述性质变化的关联;设计土柱淋溶试验模拟降雨环境,探究改良剂对磷尾矿磷含量的改良效果。经实验数据对比分析,当填料SZ添加量为15%、堆肥为12%、固磷剂FP-1为0.15%、团粒剂为0.02%时,淋滤液磷酸盐含量仅为0.18 mg/L(以P计),相较于对照处理CK,磷含量大幅下降97.8%,入渗率从7.464 mm/h提升至8.508 mm/h,pH值从6.87调整为7.23,EC值从2.625 mS/cm降低至0.961 mS/cm。中试试验深入实施阶段,对基质土进行物化性质分析,包括pH值、EC值、有机质、养分、重金属等检测指标,均达到《绿化种植土壤》(CJ/T 340—2016)行业标准;渗滤液水质分析表明,pH值、EC值、磷酸盐、氟化物、重金属等重要检测指标均符合《污水综合排放标准》(GB 8978—1996)国家标准;各试验区内植物生长态势良好,验证了磷尾矿基矿山复垦基质土与种植方案的有效性。

       

      Abstract: The Kunyang Phosphate Mine is situated within the water quality protection area of Dianchi Lake in Kunming, Yunnan Province. Mine reclamation and ecological restoration hold significant importance for safeguarding the aquatic environment of Dianchi Lake. Utilizing a substantial quantity of phosphate tailings generated from the flotation process of the Kunyang Phosphate Mine, efforts are made to enhance the substrate soil for mine reclamation. Through soil column leaching experiments, effective ecological restoration methodologies have been devised. Subsequently, the feasibility and effectiveness of these methods have been validated during pilot tests, thereby presenting novel concepts and directions for mine reclamation within the basin. During the improvement experiment phase, with phosphate tailings serving as the substrate, black shale, fillers, compost, phosphate-fixing agents, and granulating agents are selected as modifiers. The factors influencing the properties of the substrate soil, such as infiltration rate, pH value, bulk density, and saturated water content, are investigated. The correlations between varying addition amounts of each modifier and the alterations in the aforementioned properties of the substrate soil are also ascertained. Soil column leaching experiments are designed to mimic the rainfall environment and explore the ameliorative impact of the modifiers on the phosphate content of the phosphate tailings. Upon comparing and analyzing the experimental data, it is observed that when the addition amount of filler SZ reaches 15%, compost is 12%, phosphate-fixing agent FP-1 is 0.15%, and granulating agent is 0.02%, the phosphate content in the leachate is merely 0.18 mg/L(in terms of P). In contrast to the control treatment CK, the phosphate content experiences a significant reduction of 97.8%, the infiltration rate escalates from 7.464 mm/h to 8.508 mm/h, the pH value is adjusted from 6.87 to 7.23, and the EC value diminishes from 2.625 mS/cm to 0.961 mS/cm. In the in-depth implementation stage of the pilot test, an analysis of the physical and chemical properties of the substrate soil is conducted, covering detection indices such as pH value, EC value, organic matter, nutrients, and heavy metals, all of these meet the industry standard of “Soil for Greening and Planting”(CJ/T 340—2016). Simultaneously, an examination of the leachate water quality is carried out, key detection indicators like pH value, EC value, phosphate, fluoride, and heavy metals all conform to the national standard of “Integrated Wastewater Discharge Standard” (GB 8978—1996). The growth of plants in each experimental area is in good condition, verifying the effectiveness of the substrate soil and planting plan for the reclamation of phosphorus tailings base mines.

       

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