广西合浦天然石英砂矿的矿石类型及高纯石英应用潜力分析

    Ore types and analysis of high purity quartz application potential of the natural quartz sand deposit in Hepu, Guangxi

    • 摘要: 广西合浦天然石英砂矿是我国超白玻璃用低铁石英砂(水洗砂)的重要原料基地。为了给该石英矿的高效利用提供科学依据,探索其高纯石英应用潜力,采用高纯石英提纯加工技术和ICP-OES、SEM-EDS、XRD等现代分析测试方法,系统研究了矿区代表性矿点不同粒级样品的组成结构和提纯加工效果等矿物材料学特征,提出了矿石类型划分的新方案,并对不同矿石类型工业应用潜力进行了分析,研究结果表明:①该矿床主要为古河槽沉积成因,根据矿石粒度大小与物质来源、SiO2含量与提纯加工效果及工业应用潜力,将广西合浦天然石英砂矿划分为三种矿石类型:砾石矿(>2 cm)、粗砂矿(20~0.43 mm)和细砂矿(−0.43 mm)。②发现砾石矿的物质来源为脉石英,砾石矿原矿平均SiO2含量为99.981%,平均Fe和Ti含量分别≤30×10−6 和5×10−6,酸洗砂平均SiO2含量≥99.995%(4N5),个别样品氯化焙烧后SiO2纯度可达到4N8,符合高纯石英矿的纯度标准,具有开发4N5高纯石英中高端产品的潜力。③粗砂矿的物质来源主要为脉石英,其水洗砂的平均SiO2含量为99.936%,平均Fe和Ti含量分别≤30×10−6和83×10−6,是加工超白玻璃用低铁石英砂的主要原料;酸洗砂平均SiO2含量≥99.988%(3N8),具有开发集成电路用高端硅微粉等产品的潜力。④细砂矿的物质来源主要为花岗石风化产物,其水洗砂的平均SiO2含量为99.736%,平均Fe含量≤302×10−6,可加工精制石英砂;若按不高于13%的比例与粗砂矿混配使用,可用作超白玻璃用低铁石英砂原料。

       

      Abstract: Natural quartz sand mine in Hepu, Guangxi is an important raw material based for low-iron quartz sand(washed sand) used in ultra-clear glass in China. In order to provide a scientific basis for the efficient utilization of this quartz ore and explore its application potential of high purity quartz, the purification and processing technology of high purity quartz and modern analytical and testing methods such as ICP-OES, SEM-EDS and XRD are adopted to systematically study the mineral materials characteristics such as the composition structure and purification and processing effect of samples of different particle sizes at the representative mineral point in the mining area. A new classification scheme for the ore types is proposed, and the industrial application potential of different ore types is analyzed. The results show that: ① This deposit is mainly caused by the sedimentary formation of ancient river channels. According to the particle size and material source of the ore, the SiO2 content and purification processing effect, as well as the industrial application potential, the natural quartz sand ore in Hepu, Guangxi is classified into three ore types: gravel ore (>2 cm), coarse sand ore (20−0.43 mm), and fine sand ore (−0.43mm). ② It is found that the material source of the gravel ore is vein quartz. The average SiO2 content of the raw gravel ore is 99.981%, and the average Fe and Ti contents are ≤30×10−6 and 5×10−6 respectively. The average SiO2 content of acid washed sand is ≥99.995%(4N5). After chlorination roasting, the purity of SiO2 in some individual samples can reach 4N8. It meets the purity standards of high purity quartz ore and has the potential to develop 4N5 intermediary grade products of high purity quartz. ③ Material source of coarse sand ore is mainly vein quartz. The average SiO2 content of its washed sand is 99.936%, and the average Fe and Ti contents are ≤30×10−6 and 83×10−6 respectively. It is the main raw material for low-iron quartz sand used in processing ultra-clear glass. The average SiO2 content of acid washed sand is ≥99.988%(3N8), and it has the potential to develop high-end silicon micropowder and other products for integrated circuits. ④ Material source of fine sand ore is mainly the weathering products of granite. The average SiO2 content of its washed sand is 99.736%, and the average Fe content is ≤302×10−6, which can be processed into refined quartz sand. If it is mixed with coarse sand ore at a ratio not exceeding 13%, it can be used as raw material for low-iron quartz sand for ultra-clear glass.

       

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