Mn-Cu耦合低温等离子体净化矿用柴油车尾气实验研究

    Experimental study on mining diesel exhaust purification using Mn-Cu coupled low-temperature plasma

    • 摘要: 矿用柴油车尾气中的碳烟颗粒物(PM)和气相非甲烷总烃(THC)是形成二次气溶胶及臭氧的关键前体物,然而现有DPF/DOC技术在低温活性、能耗及变工况适应性方面仍存在显著瓶颈。为突破上述局限,以同轴圆筒式介质阻挡放电(DBD)低温等离子体反应器为核心,耦合碳质锰基金属氧化物复合负载型氧化催化剂,系统考察放电电压、尾气流量及初始浓度对PM和THC协同脱除的影响机制。实验结果表明:PM净化效率随电压升高(13~17 kV)而提高,但随流量(2~5 L/min)或浓度(33.75~99.40 mg/L)增加呈显著下降;正交试验确定最优工况17 kV、3 L/min、50.10 mg/L,PM去除率52.7%。THC研究进一步发现,400 g催化剂填充时,17 kV、3 L/min、120.00 mg/L条件下THC去除率达59.2%;催化剂有效缓解高流量/高浓度导致的效率衰减,揭示了“等离子体活化-催化氧化”协同机制。

       

      Abstract: PM and THC of mining diesel are key precursors of secondary aerosols and ozone, yet conventional DPF/DOC systems suffer from low-temperature inactivity, high energy demand and poor load flexibility. This paper couples a coaxial DBD plasma reactor with a Mn-oxide/carbon composite catalyst to investigate the simultaneous removal of PM and THC. PM conversion rises with applied voltage(13-17 kV) but dropped markedly when flow rate(2-5 L/min) or inlet concentration(33.75-99.4 mg/L) increases. Orthogonal tests yield the optimum at 17 kV, 3L/min and 50.1 mg/L, giving 52.7% PM removal. With 400 g catalyst, THC removal reaches 59.2% at 17 kV, 3 L/min and 120 mg/L; the catalyst alleviates efficiency loss under high flow and concentration, evidencing a plasma-activation/catalytic-oxidation synergy.

       

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