石墨尾矿中关键战略金属提取研究进展

    Research progress on the extraction of key strategic metals from graphite tailings

    • 摘要: 石墨尾矿作为典型的多金属伴生二次资源,富含钒、铁、锂、钛及稀土元素等关键战略金属,但其利用率长期较低,大多采用堆存处理。加快石墨尾矿中战略金属的高效提取和综合利用研究,对于保障国家资源安全、促进绿色矿业发展具有重大战略意义。本文系统总结了石墨尾矿中不同战略金属在提取过程中的赋存状态转化机制与回收规律,重点评述以物理分选和化学浸出为核心的提取技术进展。物理分选技术包括浮选法、磁选法和重选法等,其中浮选法通过优化捕收剂体系和工艺流程设计,可显著提高钒、铁、锂、钛等金属的回收效率和选择性;磁选法则利用磁性的差异来实现钒和铁的高效富集;重选法则适用于钛的回收。化学浸出技术包括酸浸法、碱浸法和焙烧浸出法等,酸浸法通过硫酸、草酸等试剂破坏矿物晶格,实现锂和稀土的高效浸出;碱浸法利用高温高浓度碱液选择性溶解锂或通过离子交换释放锂,浸出率较高且环境压力较小;焙烧浸出法通过高温焙烧预处理,使钒、铁等金属转化为易浸出形态,再结合酸浸或碱浸提高回收率。然而,当前研究仍面临矿物赋存状态复杂导致的解离困难,多金属协同回收体系的缺乏及存在二次环境污染风险等问题。通过优化浮选药剂、浸出工艺及多金属协同回收体系,提高目标金属的回收率并降低试剂与能耗成本,从而显著提升整体经济效益,在绿色高效、资源循环、工艺集成等方面展现出良好的工业应用前景与资源循环价值。未来研究需着力突破关键技术瓶颈,深化基础理论认识并开发创新工艺,为实现石墨尾矿资源高值化利用提供理论与经济的双重支撑,推动矿产资源可持续发展和国家“双碳”战略目标的实现。

       

      Abstract: As a typical multi-metal associated secondary resource, graphite tailings are rich in key strategic metals such as vanadium, iron, lithium, titanium and rare earth elements. However, the utilization rate of graphite tailings is low for a long time, and most of them are stacked. Accelerating the efficient extraction and comprehensive utilization of strategic metals in graphite tailings is of great strategic significance for ensuring national resource security and promoting the development of green mining. This paper systematically summarizes the occurrence state transformation mechanism and recovery law of different strategic metals in graphite tailings during the extraction process, and focuses on the progress of extraction technology with physical separation and chemical leaching as the core. Physical separation technology includes flotation method, magnetic separation method and gravity separation method. The flotation method can significantly improve the recovery efficiency and selectivity of vanadium, iron, lithium, titanium and other metals by optimizing the collector system and process design. Magnetic separation method utilizes the difference of magnetism to achieve efficient enrichment of vanadium and iron. The reelection rule is applicable to the recovery of titanium. Chemical leaching technology includes acid leaching, alkali leaching and roasting leaching. The acid leaching method destroys the mineral lattice by sulfuric acid, oxalic acid and other reagents to achieve efficient leaching of lithium and rare earth. The alkali leaching method uses high temperature and high concentration lye to selectively dissolve lithium or release lithium through ion exchange, which has high leaching rate and low environmental pressure. The roasting leaching method converts vanadium, iron and other metals into easy leaching forms by high temperature roasting pretreatment, and then combines acid leaching or alkali leaching to improve the recovery rate. However, the current research still faces problems such as the difficulty of dissociation caused by the complex occurrence of minerals, the lack of a multi-metal collaborative recovery system, and the risk of secondary environmental pollution. By optimizing flotation reagents, leaching processes and multi-metal synergistic recovery systems, the recovery rate of target metals is improved and the cost of reagents and energy consumption is reduced, thereby significantly improving the overall economic benefits. It shows good industrial application prospects and resource recycling value in green and efficient, resource recycling, and process integration. Future research should focus on breaking through the bottleneck of key technologies, deepening the understanding of basic theories and developing innovative processes, so as to provide theoretical and economic support for the high-value utilization of graphite tailings resources, and promote the sustainable development of mineral resources and the realization of the national “double carbon” strategic goal.

       

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