不同级配硅铝酸盐水泥与高炉渣基复合注浆材料性能研究

    Study on the properties of different gradation silicoaluminate cement and blast furnace slag based composite grouting materials

    • 摘要: 硅酸盐水泥胶凝时间长,早期强度低,后期强度增长明显。硫铝酸盐水泥具有快硬和早强等优点,但后期强度增长不明显。选择合适的硅铝酸盐水泥复配比,能使其优异性能互补。而高炉渣、粉煤灰作为工业固废常被遗弃,对生态环境造成一定的影响。高炉渣通常分为缓冷渣和砂状水淬渣,可用于水泥生产原料和混凝土骨料。因此,以高炉渣为主、粉煤灰为辅,制备煤基固废水泥注浆材料,并以硅酸盐水泥和硫铝酸盐水泥为胶凝材料,研究不同级配硅酸盐水泥和硫铝酸盐水泥复配占比,对煤基固废水泥注浆材料力学性能及流动性能进行研究。采用SEM对注浆材料元素占比开展分析,注浆材料主要水化产物为C—A—S—H凝胶,当硅酸盐水泥和硫铝酸盐水泥质量比2∶3时,与高炉渣粉骨料、粉煤灰、C—S—H凝胶形成的骨架互相加固最佳。试件28 d抗压强度和抗折强度分别为18.63 MPa和4.77 MPa,坍落度为36.12 cm,凝结时间为102 min,综合性能最优。此研究对煤基固废注浆材料的研发和应用具有一定的理论价值。

       

      Abstract: Silicate cement exhibits prolonged setting time and low early strength, with significant strength gain occurring in later stages. While sulfoaluminate cement demonstrates rapid hardening and early strength advantages, its post-hardening strength growth remains limited. Optimizing silicoaluminate cement mix ratios enables complementary advantages of these materials. However, industrial solid wastes like blast furnace slag and fly ash, often discarded, pose environmental challenges. Blast furnace slag (classified as slow-cooling slag or sand-like water-quenched slag) serves as raw material for cement production and concrete aggregates. This study developed coal-based cement grouting materials using blast furnace slag as primary component and fly ash as supplementary material, employing silicate and sulfoaluminate cements as binders. The research evaluates mechanical and flow properties of different silicate-sulfoaluminate cement mix proportions. SEM analysis revealed C—A—S—H gel formation as the primary hydration product. Optimal reinforcement occurred when silicate-to-sulfoaluminate cement ratios are 2∶3, combined with blast furnace slag powder aggregates, fly ash, and C—S—H gel. Test specimens achieved 28-day compressive strength 18.63 MPa, flexural strength 4.77 MPa, slump 36.12cm, and setting time of 102 min, demonstrating superior performance. This research provides theoretical foundations for developing and applying coal-based cement grouting materials.

       

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