三塘湖富油煤热作用下孔渗特征与物理性质研究

    Study on the porosity and permeability characteristics and physical properties of oil-rich coal under thermal action in Santanghu Area

    • 摘要: 三塘湖盆地白石湖矿区与石头梅矿区富油煤在热作用下孔渗演化与物理性质出现显著差异变化,直接影响煤样的热解工艺参数设置。白石湖煤样以高镜质组、高挥发分、高焦油产率为特征,热演化中呈现“阶梯式”变化,300~400 ℃生油高峰期孔隙度骤降至8.0%,渗透率由478.5 mD跌至77.6 mD,热导率形成低谷(0.275 W/(m·K)),呈现热塑性堵塞效应。石头梅煤样则以中高镜质组、高惰质组、高固定碳为特征,孔渗参数随温度单调递增,600 ℃时孔隙度达27.71%、渗透率537.6 mD,热导率平稳上升,反应活性始终优于白石湖煤样。微观结构表明,白石湖煤样渗流依赖裂隙与热解气孔,石头梅煤样依托原生胞腔孔形成立体网络。因此,提出白石湖宜“先提油后半焦气化”、石头梅适合作气化原料的梯级利用路径。

       

      Abstract: The thermal evolution of porosity and permeability, as well as the physical properties, of Baishihu and Shitoumei mining areas oil-rich coal in the Santanghu Basin exhibit significant differences, directly affecting the setting of pyrolysis process parameters for coal samples. Baishihu coal is characterized by high vitrinite content, high volatile matter, and high tar yield. During thermal evolution, it exhibits a “stepped” change, with porosity plummeting to 8.0% and permeability dropping from 478.5 mD to 77.6 mD during the peak oil generation period at 300-400 ℃, resulting in a trough in thermal conductivity (0.275 W/(m·K)) and exhibiting a thermoplastic plugging effect. Shitoumei coal, on the other hand, is characterized by medium-high vitrinite content, high inertinite content, and high fixed carbon. Its porosity and permeability parameters increase monotonically with temperature, reaching 27.71% porosity and 537.6 mD permeability at 600 ℃, with a steady increase in thermal conductivity. Its reactivity is consistently superior to that of Baishihu coal. Microscopic analysis indicates that Baishihu coal seepage relies on fractures and pyrolysis pores, while Shitoumei coal relies on primary cell cavities to form a three-dimensional network. Therefore, it is proposed that Baishihu should be used for “oil extraction followed by semi-coke gasification” and Shitoumei is suitable for a cascade utilization path as gasification feedstock.

       

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