Analysis of pollution characteristics and risk assessment of heavy metals in surrounding soils of gangue piling site

    • 摘要: 本文红沙泉露天煤矿作为研究区,采取描述统计、主成分分析和污染评价方法,对煤矸石堆场周围不同距离土壤中Zn、Cu、Cr、Hg、As和Pb的含量和及其污染特征进行分析与评价。结果表明:土壤中Cr和As含量超过了新疆背景值,分别为2.15倍和2.31倍,国家标准值(国家土壤环境二级标准值)1.74倍和2.31倍。土壤中Hg含量超过了新疆背景值,低于国家标准值。土壤重金属含量的大小顺序分别为Cr>Zn>As>Cu>Pb>Hg。土壤重金属含量相关性来看,P<0.01水平上Zn和Cu呈显著性正相关,这两个元素来自于土壤母质。因子2主要由Cr和As组成,来自于人为因素。P<0.01水平上Hg和Pb具有较好的相关性(相关系数0.46),来自于煤矸石堆场。土壤重金属含量在不同距离上的分布来看,Zn和Cu含量分布的比较均匀,Cr和As含量在不同距离中的分布没有一定的规律,煤矸石堆场对周围土壤中Hg和Pb的影响范围为50~350 m,超过350 m之后煤矸石堆场对土壤的影响不太明显。土壤重金属污染分析可知,土壤中Zn、Cu和Pb处于轻度污染,Cr、Hg和As处于重度污染状态。

       

      Abstract: In this paper,an example of the Hongshaquan pit coal mining area,analysis and assessment of the different distance heavy metals in soils of the gangue piling sites.Analyzing heavy metals including Zn,Cu,Cr,Hg,As and Pb,this study using multivariate statistical analysis,principal component analysis,pollution assessment and based on the laboratory analysis on the soil samples collected from study site.The results showed that:Soil heavy metal contents of Cr and As were higher than the regional background value 2.15 and 2.31 times and higher than the second grade national standard of soil environment quality standard (GB15618-1995)1.74 and 2.31times;Hg higher than the regional background and lower than the soil environment quality standard.The amount of soil heavy metal contents were in the order as Cr>Zn>As>Cu>Pb>Hg;From the relativity of heavy metals in soil was found that,significant relationship between Zn and Cu in P<0.01 level,and it was comes from the soil parent material.Factor 2 component Cr and As,and it was comes from the human factor.Significant relationship between Hg and Pb in P < 0.01 level,and it was comes from the gangue piling site.From the distribution of the heavy metals in different distance can be seen,Zn and Cu distributed uniformly,along with variation of the distance Cr and As haven’t any regularly distributed,influence region of gangue piling sites on Hg and Pb in soil 50 - 350 m.Evaluation results based on the pollution index indicated that soils were severely and slightly polluted by Cr,Hg,As and Zn,Cu,Pb.

       

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