Abstract: Copper is one of pernicious metals that come into being longer effect to people's health, along with its compounds. The wastewater contained copper should be treated before draining off to water body. Based on the exposition for treatment methodology of wastewater contained copper, the experiments of wastewater treatment of copper had been done with fly ash zeolite and treatment technology was explored also, the optimal parameters were obtained finally. According with the experiments for getting rid of copper from wastewater, the fly ash zeolite is a kind of excellent water treatment reagent for wastewater contained copper, and it will have spacious applied prospect in the realm of water treatment.