马晓敏, 樊玉萍, 董宪姝, 侯金瑛, 常明. 药剂吸附与剪切条件对煤泥水絮凝效果的影响[J]. 中国矿业, 2019, 28(4): 156-162. DOI: 10.12075/j.issn.1004-4051.2019.04.014
    引用本文: 马晓敏, 樊玉萍, 董宪姝, 侯金瑛, 常明. 药剂吸附与剪切条件对煤泥水絮凝效果的影响[J]. 中国矿业, 2019, 28(4): 156-162. DOI: 10.12075/j.issn.1004-4051.2019.04.014
    MA Xiaomin, FAN Yuping, DONG Xianshu, HOU Jinying, CHANG Ming. Effect of flocculant adsorption and shearing strength on flocculation efficiency of coal slurry[J]. CHINA MINING MAGAZINE, 2019, 28(4): 156-162. DOI: 10.12075/j.issn.1004-4051.2019.04.014
    Citation: MA Xiaomin, FAN Yuping, DONG Xianshu, HOU Jinying, CHANG Ming. Effect of flocculant adsorption and shearing strength on flocculation efficiency of coal slurry[J]. CHINA MINING MAGAZINE, 2019, 28(4): 156-162. DOI: 10.12075/j.issn.1004-4051.2019.04.014

    药剂吸附与剪切条件对煤泥水絮凝效果的影响

    Effect of flocculant adsorption and shearing strength on flocculation efficiency of coal slurry

    • 摘要: 煤泥水处理是选煤生产的重点和难点环节,本文从煤泥水和药剂的基本性质入手,结合沉降试验、剪切试验、吸附试验和X射线光电子能谱分析等研究了阴离子聚丙烯酰胺(APAM)吸附与剪切条件对煤泥水絮凝效果的影响。结果表明:剪切条件和APAM用量对煤泥水的絮凝效果有很大影响,APAM在煤泥上的饱和吸附量约为0.74 mg/g; 随着APAM用量的增加,APAM吸附效率降低,在用量为0.6~0.8 kg/t时,APAM吸附效率为63%~51%,对应的透射比在90%以上,澄清度和除浊效果最好,说明APAM药剂的吸附效率与其絮凝效果密切相关。APAM在煤泥上的吸附使得含C峰和含N峰发生了一些变化,C—C和C=O及C—N官能团有所增多。高药剂量可以提供一定的抗剪切特性,提高絮团的再絮凝能力。通过控制药剂量和剪切条件可以调控絮团结构和絮凝沉降效果,提高煤泥水固液分离效率。

       

      Abstract: Coal slurry treatment is a crucial and difficult link in coal preparation.Based on the basic properties of coal slurry, this paper studies the effects of the adsorption of anionic polyacrylamide (APAM) and shearing strength on the flocculation performance of coal slurry combined with the settlement experiment, shear experiment, adsorption experiment and X ray photoelectron spectroscopy analysis, etc.The results show that the dosage of APAM and shearing strength have great influence on the flocculation of coal slurry.The saturated adsorption amount of APAM is about 0.74 mg/g.With the increase of the APAM dosage, the adsorption efficiency of APAM reduces.When the dosage of APAM is 0.6~0.8 kg/t, the adsorption efficiency of APAM is 63%~51%.The corresponding transmission ratio is above 90% and the clarification and turbidity removal efficiency are the best.This means that the clarification effect is closely related to the adsorption efficiency.The adsorption of the APAM on the slurry makes some changes in the C and N peaks, resulting in the increase of the C—C and C=O and C—N functional groups.The high dosage can protect floc from breakage and enhance its recovery ability.The floc structure and the effect of flocculation and settling of coal slurry can be controlled by the dosage of reagent and shearing strength, thus, the solid-liquid separation efficiency of coal slurry can be improved.

       

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