杨秀敏. 凹凸棒石对Zn2+、Cu2+、Cd2+的等温吸附实验研究[J]. 中国矿业, 2020, 29(11): 94-99. DOI: 10.12075/j.issn.1004-4051.2020.11.028
    引用本文: 杨秀敏. 凹凸棒石对Zn2+、Cu2+、Cd2+的等温吸附实验研究[J]. 中国矿业, 2020, 29(11): 94-99. DOI: 10.12075/j.issn.1004-4051.2020.11.028
    YANG Xiumin. Study of attapulgite on the isotherm adsorption of Zn2+, Cu2+ and Cd2+[J]. CHINA MINING MAGAZINE, 2020, 29(11): 94-99. DOI: 10.12075/j.issn.1004-4051.2020.11.028
    Citation: YANG Xiumin. Study of attapulgite on the isotherm adsorption of Zn2+, Cu2+ and Cd2+[J]. CHINA MINING MAGAZINE, 2020, 29(11): 94-99. DOI: 10.12075/j.issn.1004-4051.2020.11.028

    凹凸棒石对Zn2+、Cu2+、Cd2+的等温吸附实验研究

    Study of attapulgite on the isotherm adsorption of Zn2+, Cu2+ and Cd2+

    • 摘要: 凹凸棒石是一种比表面积大,吸附能力强的天然黏土矿物。为了研究凹凸棒石的吸附特征,通过等温吸附实验,进行了凹凸棒石对复合重金属离子Zn2+、Cu2+、Cd2+的吸附容量、去除率、吸附选择性和富集系数的研究。结果表明:凹凸棒石对Zn2+、Cu2+、Cd2+吸附容量表现为随溶液初始浓度的增加而增加,吸附选择特征表现为对Cu2+的吸附大于对Zn2+和Cd2+的吸附。当重金属离子初始浓度在20 mg/L时凹凸棒石对Cu2+的去除率为97.40%,而对Zn2+、Cd2+的去除率分别为96.76%和96.22%;当浓度增加到300 mg/L时,对Cu2+的去除率降低至73.19%,而对Zn2+、Cd2+的去除率降至48.18%和38.84%。富集系数与吸附特征反应的结果一致,并且吸附符合Langmuir方程和Freundlich方程。研究结果表明凹凸棒石可用于水体和土壤重金属污染的修复。

       

      Abstract: Attapulgite is a natural clay mineral with large specific surface and strong adsorption ability.The given paper is aimed to make an exploration of adsorption characteristics of attapulgite on the heavy metal ion Zn2+, Cu2+and Cd2+, the adsorption capacity, removal rate, adsorption selectivity and enrichment coefficients of heavy metal ions Zn2+, Cu2+and Cd2+ by using attapulgite were studied through the adsorption isotherm experiment.The results show that the adsorption capacity of attapulgite to Cu2+, Zn2+and Cd2+ increased with the increase of the initial concentration of the solution, and the characteristics of adsorption selection are Cu2+ > Zn2+ > Cd2+.The removal rate of Cu2+ by attapulgite was 97.40%, Zn2+ and Cd2+ by was 96.76% and 96.22%, respectively, when the initial concentration of attapulgite was 20 mg/L.When the concentration increased to 300 mg/L, the removal rate of Cu2+decreased to 73.19%, the removal rate of Zn2+ and Cd2+ decreased to 48.18% and 38.84%.The enrichment coefficient is consistent with the result of adsorption characteristic, and the adsorption accords with Langmuir and Freundlich equations.The results show that attapulgite can be used for remediation of heavy metal pollution in water and soil.

       

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