赵文华, 崔锋, 刘鹏亮, 王浩宇. 粉煤灰-脱硫石膏充填材料性能及微观结构研究[J]. 中国矿业, 2022, 31(9): 132-138. DOI: 10.12075/j.issn.1004-4051.2022.09.010
    引用本文: 赵文华, 崔锋, 刘鹏亮, 王浩宇. 粉煤灰-脱硫石膏充填材料性能及微观结构研究[J]. 中国矿业, 2022, 31(9): 132-138. DOI: 10.12075/j.issn.1004-4051.2022.09.010
    ZHAO Wenhua, CUI Feng, LIU Pengliang, WANG Haoyu. Study on properties and microstructure of fly ash-flue gas desulphurization gypsum filling material[J]. CHINA MINING MAGAZINE, 2022, 31(9): 132-138. DOI: 10.12075/j.issn.1004-4051.2022.09.010
    Citation: ZHAO Wenhua, CUI Feng, LIU Pengliang, WANG Haoyu. Study on properties and microstructure of fly ash-flue gas desulphurization gypsum filling material[J]. CHINA MINING MAGAZINE, 2022, 31(9): 132-138. DOI: 10.12075/j.issn.1004-4051.2022.09.010

    粉煤灰-脱硫石膏充填材料性能及微观结构研究

    Study on properties and microstructure of fly ash-flue gas desulphurization gypsum filling material

    • 摘要: 为了有效处理电厂的两大工业废渣粉煤灰和脱硫石膏,实现火电厂固废资源化利用,将粉煤灰和脱硫石膏与生石灰、水泥以适当比例混合,通过开展泌水率、流动度、单轴抗压强度、X射线衍射、扫描电镜等试验,综合考虑流动性能和力学性能,得到适宜煤矿充填的粉煤灰-脱硫石膏充填材料配比方案。研究结果表明:粉煤灰、脱硫石膏、生石灰、水泥以3∶1∶1∶1配比时,该矿物掺和料的料浆流动度可达300 mm以上,泌水率为4.71%。充填体7 d抗压强度大于3 MPa,28 d抗压强度大于4 MPa;随着粉煤灰与脱硫石膏比例的增加,3 d、7 d强度逐渐增大,14 d、28 d强度呈现先增大后减小的规律。粉煤灰-脱硫石膏充填材料水化产物主要包括钙矾石、水化硅酸钙、水合碳酸铝钙、二水石膏。水化产物会填充充填体内部的孔隙结构,宏观表现为提高了充填体强度。

       

      Abstract: In order to effectively dispose the fly ash (FA) and flue gas desulphurization gypsum (FGD), two major industrial wastes of power plants, to realize the resource utilization of solid waste in thermal power plants, the FA and FGD are mixed with quicklime and cement in appropriate proportions, and conducting experiments such as bleeding rate, fluidity, uniaxial compressive strength, X-ray direction (XRD), scanning electron microscopy(SEM), and comprehensively considering flow properties and mechanical properties to obtain suitable coal mines.Filled FA and FGD filling material ratio scheme.The results show that when the ratio of FA, FGD, quicklime and cement is 3:1:1:1, the slurry fluidity of the mineral admixture can reach more than 300 mm and the bleeding rate is 4.71%.The 7 d compressive strength of the backfill is greater than 3 MPa, and the 28 d compressive strength is higher than 4 MPa.With the increase of the ratio of FA and FGD, the 3 d, 7 d strength increases gradually, and the 14 d, 28 d strength increases first and then decreases.The hydration products of FA and FGD filling material mainly include ettringite, hydrated calcium silicate, hydrated calcium aluminum carbonate, and gypsum.The hydration product will fill the pore structure inside the filling body, and the macroscopic performance is to improve the strength of the filling body.

       

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