THEORETICAL CACULATING THE LIGAND-FIELD TRANSITION FREQUENT OF FERROUS INOS OF M<sub>1</sub> SITE IN THE CRYSTAL STRUCTURE OF JADEITE

Song Mianxin; Yi Facheng

Song Mianxin, Yi Facheng. THEORETICAL CACULATING THE LIGAND-FIELD TRANSITION FREQUENT OF FERROUS INOS OF M1 SITE IN THE CRYSTAL STRUCTURE OF JADEITEJ. CHINA MINING MAGAZINE, 2004, 13(11): 67-68.

Citation:

Song Mianxin, Yi Facheng. THEORETICAL CACULATING THE LIGAND-FIELD TRANSITION FREQUENT OF FERROUS INOS OF M1 SITE IN THE CRYSTAL STRUCTURE OF JADEITEJ. CHINA MINING MAGAZINE, 2004, 13(11): 67-68.

Citation:

Song Mianxin, Yi Facheng. THEORETICAL CACULATING THE LIGAND-FIELD TRANSITION FREQUENT OF FERROUS INOS OF M1 SITE IN THE CRYSTAL STRUCTURE OF JADEITEJ. CHINA MINING MAGAZINE, 2004, 13(11): 67-68.

THEORETICAL CACULATING THE LIGAND-FIELD TRANSITION FREQUENT OF FERROUS INOS OF M₁ SITE IN THE CRYSTAL STRUCTURE OF JADEITE

Abstract

Abstract

THe 3d radical wave function of Fe²⁺ ions proposed by Zhao and the calculating method of the ligand-field transition of Fe²⁺ ions of M 1 site in the crystal structure of diopside used by Xue were adopted in this paper.The calculated results show that there are three spin-allowed spectra of Fe²⁺ ions of M 1 site.The calculated energy of 9767cm^-1 among these is in reasonable agreement with energy of stronger band 9718-9633cm^-1 observed in the optical spectra of jadeite.

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THEORETICAL CACULATING THE LIGAND-FIELD TRANSITION FREQUENT OF FERROUS INOS OF M1 SITE IN THE CRYSTAL STRUCTURE OF JADEITE

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THEORETICAL CACULATING THE LIGAND-FIELD TRANSITION FREQUENT OF FERROUS INOS OF M₁ SITE IN THE CRYSTAL STRUCTURE OF JADEITE